Highly sensitive electrochemical determination of rutin based on the synergistic effect of 3D porous carbon and cobalt tungstate nanosheets

Guangjun Feng; Yang Yang; Jiantao Zeng; Jun Zhu; Jingjian Liu; Lun Wu; Zhiming Yang; Guanyi Yang; Quanxi Mei; Qinhua Chen; Fengying Ran

doi:10.1016/j.jpha.2021.09.007

Volume 12 Issue 3

Jun. 2022

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Article Navigation > Journal of Pharmaceutical Analysis > 2022 > 12(3): 453-459

Guangjun Feng, Yang Yang, Jiantao Zeng, Jun Zhu, Jingjian Liu, Lun Wu, Zhiming Yang, Guanyi Yang, Quanxi Mei, Qinhua Chen, Fengying Ran. Highly sensitive electrochemical determination of rutin based on the synergistic effect of 3D porous carbon and cobalt tungstate nanosheets[J]. Journal of Pharmaceutical Analysis, 2022, 12(3): 453-459. doi: 10.1016/j.jpha.2021.09.007

Citation:

Guangjun Feng, Yang Yang, Jiantao Zeng, Jun Zhu, Jingjian Liu, Lun Wu, Zhiming Yang, Guanyi Yang, Quanxi Mei, Qinhua Chen, Fengying Ran. Highly sensitive electrochemical determination of rutin based on the synergistic effect of 3D porous carbon and cobalt tungstate nanosheets[J]. Journal of Pharmaceutical Analysis, 2022, 12(3): 453-459. doi: 10.1016/j.jpha.2021.09.007

Citation:

Guangjun Feng, Yang Yang, Jiantao Zeng, Jun Zhu, Jingjian Liu, Lun Wu, Zhiming Yang, Guanyi Yang, Quanxi Mei, Qinhua Chen, Fengying Ran. Highly sensitive electrochemical determination of rutin based on the synergistic effect of 3D porous carbon and cobalt tungstate nanosheets[J]. Journal of Pharmaceutical Analysis, 2022, 12(3): 453-459. doi: 10.1016/j.jpha.2021.09.007

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Highly sensitive electrochemical determination of rutin based on the synergistic effect of 3D porous carbon and cobalt tungstate nanosheets

doi: 10.1016/j.jpha.2021.09.007

a. Shenzhen Baoan Authentic TCM Therapy Hospital, Shenzhen, 518101, China;
b. Sinopharm Dongfeng General Hospital, Hubei University of Medicine, Shiyan, Hubei, 442008, China;
c. Shenzhen Hospital of Integrated Traditional Chinese and Western Medicine, Shenzhen, 518101, China

Funds:

This work was financially supported by the National Natural Science Foundation of China (Grant No.: 81872509) and the Baoan TCM Development Foundation (Grant No.: 2020KJCX-KTYJ-200), Internal Research Project of the Shenzhen Baoan Authentic TCM Therapy Hospital (Grant Nos.: BCZY2021003 and BCZY2021007), Baoan District Medical and Health Basic Research Project (Grant No.: 2020JD491), Natural Science Foundation of Hubei Province (Grant No.: 2019CFB429), Chinese Medicine Research Fund of Health Commission of Hubei Province (Grant Nos.: ZY2021M038 and ZY2021M051), the Youth Talent Project of Sinopharm Dongfeng General Hospital (Grant No.: 2021Q03), the Science and Technology Key Program of Shiyan (Grant No.: 21Y77), Baoan District Medical and Health Basic Research Project (Grant Nos.: 2021JD143, 2021JD281, and 2021JD290), Hubei Province Health and Family Planning Scientific Research Project (Grant Nos.: WJ2021M063 and WJ2021M062), and Sanming Project of Medicine in Shenzhen (Grant No.: SZZYSM202106004).

Received Date: Mar. 06, 2021
Accepted Date: Sep. 15, 2021
Rev Recd Date: Sep. 07, 2021
Publish Date: Sep. 16, 2021

Abstract

Abstract

Rutin, a flavonoid found in fruits and vegetables, is a potential anticancer compound with strong anticancer activity. Therefore, electrochemical sensor was developed for the detection of rutin. In this study, CoWO₄ nanosheets were synthesized via a hydrothermal method, and porous carbon (PC) was prepared via high-temperature pyrolysis. Successful preparation of the materials was confirmed, and characterization was performed by transmission electron microscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. A mixture of PC and CoWO₄ nanosheets was used as an electrode modifier to fabricate the electrochemical sensor for the electrochemical determination of rutin. The 3D CoWO₄ nanosheets exhibited high electrocatalytic activity and good stability. PC has a high surface-to-volume ratio and superior conductivity. Moreover, the hydrophobicity of PC allows large amounts of rutin to be adsorbed, thereby increasing the concentration of rutin at the electrode surface. Owing to the synergistic effect of the 3D CoWO₄ nanosheets and PC, the developed electrochemical sensor was employed to quantitively determine rutin with high stability and sensitivity. The sensor showed a good linear range (5-5000 ng/mL) with a detection limit of 0.45 ng/mL. The developed sensor was successfully applied to the determination of rutin in crushed tablets and human serum samples.
- Rutin,
- Electrochemical detection,
- CoWO₄ nanosheets,
- Porous carbon,
- Sensor

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References(41)

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