Effective extraction of fluoroquinolones from water using facile modified plant fibers

Nan Zhang; Yan Gao; Kangjia Sheng; Wanghui Jing; Xianliang Xu; Tao Bao; Sicen Wang

doi:10.1016/j.jpha.2022.06.004

Volume 12 Issue 5

Nov. 2022

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Article Navigation > Journal of Pharmaceutical Analysis > 2022 > 12(5): 791-800

Nan Zhang, Yan Gao, Kangjia Sheng, Wanghui Jing, Xianliang Xu, Tao Bao, Sicen Wang. Effective extraction of fluoroquinolones from water using facile modified plant fibers[J]. Journal of Pharmaceutical Analysis, 2022, 12(5): 791-800. doi: 10.1016/j.jpha.2022.06.004

Citation:

Nan Zhang, Yan Gao, Kangjia Sheng, Wanghui Jing, Xianliang Xu, Tao Bao, Sicen Wang. Effective extraction of fluoroquinolones from water using facile modified plant fibers[J]. Journal of Pharmaceutical Analysis, 2022, 12(5): 791-800. doi: 10.1016/j.jpha.2022.06.004

Citation:

Nan Zhang, Yan Gao, Kangjia Sheng, Wanghui Jing, Xianliang Xu, Tao Bao, Sicen Wang. Effective extraction of fluoroquinolones from water using facile modified plant fibers[J]. Journal of Pharmaceutical Analysis, 2022, 12(5): 791-800. doi: 10.1016/j.jpha.2022.06.004

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Effective extraction of fluoroquinolones from water using facile modified plant fibers

doi: 10.1016/j.jpha.2022.06.004

Nan Zhang^a,
Yan Gao^a,
Kangjia Sheng^a,
Wanghui Jing^a,b,
Xianliang Xu^a,
Tao Bao^{a,b
,
,},
Sicen Wang^{a,c
,
,}

a. School of Pharmacy, Xi'an Jiaotong University Health Science Center, Xi'an, 710061, China;
b. Institute of Chinese Medical Sciences, State Key Laboratory of Quality Research in Chinese Medicine, University of Macau, Macao, 999078, China;
c. Shaanxi Engineering Research Center of Cardiovascular Drugs Screening & Analysis, Xi'an, 710061, China

Funds:

This work was supported by the National Natural Science Foundation of China (Grant Nos.: 81703469 and 81973277), Open Fund of the State Key Laboratory of Quality Research in Chinese Medicine, University of Macau (Grant No.: SKL-QRCM(UM)-2020-2022, QRCM-OP21007), and the World-Class Universities (Disciplines) and the Characteristic Development Guidance Funds for the Central Universities (Grant No.: PY3A012).

Received Date: Jan. 02, 2022
Accepted Date: Jun. 10, 2022
Rev Recd Date: Jun. 07, 2022
Publish Date: Jun. 14, 2022

Abstract

Abstract

In this study, ecofriendly and economic carboxy-terminated plant fibers (PFs) were used as adsorbents for the effective in-syringe solid phase extraction (IS-SPE) of fluoroquinolone (FQ) residues from water. Based on the thermal esterification and etherification reaction of cellulose hydroxy with citric acid (CA) and sodium chloroacetate in aqueous solutions, carboxy groups grafted onto cotton, cattail, and corncob fibers were fabricated. Compared with carboxy-terminated corncob and cotton, CA-modified cattail with more carboxy groups showed excellent adsorption capacity for FQs. The modified cattail fibers were reproducible and reusable with relative standard deviations of 3.2%–4.2% within 10 cycles of adsorption-desorption. A good extraction efficiency of 71.3%–80.9% was achieved after optimizing the extraction condition. Based on carboxylated cattail, IS-SPE coupled with ultra-performance liquid chromatography with a photodiode array detector was conducted to analyze FQs in environmental water samples. High sensitivity with limit of detections of 0.08–0.25 μg/L and good accuracy with recoveries of 83.8%–111.7% were obtained. Overall, the simple and environment-friendly modified waste PFs have potential applications in the effective extraction and detection of FQs in natural waters.
- Fluoroquinolones,
- Cattail fiber,
- Carboxylation modification,
- In-syringe solid phase extraction

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References(48)

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